DR ANTHONY MELVIN CRASTO,WorldDrugTracker, helping millions, A 90 % paralysed man in action for you, I am suffering from transverse mylitis and bound to a wheel chair, With death on the horizon, nothing will not stop me except God
DR ANTHONY MELVIN CRASTO Ph.D ( ICT, Mumbai) , INDIA 25Yrs Exp. in the feld of Organic Chemistry,Working for GLENMARK GENERICS at Navi Mumbai, INDIA. Serving chemists around the world. Helping them with websites on Chemistry.Million hits on google, world acclamation from industry, academia, drug authorities for websites, blogs and educational contribution
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Saturday, 21 July 2012

Kharasch-Sosnovsky Reaction:


Kharasch-Sosnovsky Reaction:
copper catalysed allylic oxidation using an organic peroxide.
reported by M. S. Kharasch and George Sosnovsky in 1958 ((DOIDOI).
In the original publication the reactants are cyclohexene
and t-butyl perbenzoate with cuprous bromide and the
reaction product is cyclohex-1-en-3-yl benzoate:
 

Mechanism: (review: DOI). The reaction mechanism devised
by Beckwith et al (DOI) contains the following steps:

 


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DR ANTHONY MELVIN CRASTO Ph.D
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GLENMARK SCIENTIST , NAVIMUMBAI, INDIA
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